期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 21, 期 22, 页码 8206-8214出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1jm10326a
关键词
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资金
- Research Grants Council of the Hong Kong Special Administrative Region, China [CityU 101508]
- National Natural Science Foundation of China [91027041]
- Key Laboratory of Photochemical Conversion and Optoelectronic Materials, TIPC, CAS
A series of phenanthroimidazole derivatives have been synthesized, characterized and applied as non-doped emitters in organic light-emitting devices. The compounds show high fluorescent quantum yields up to 0.75 as well as good thermal and film-forming abilities. Crystal structures of the compounds were determined by X-ray crystallography. Correlations between optoelectronic properties, energy levels and molecular structures of the materials were investigated. It was found that introduction of a thiophene ring on the C2-position of phenanthroimidazole can effectively decrease the ionization potentials (I-p) of the compounds. Fluorescent properties of the materials were found to be related to the dihedral angles in the compounds with different substituents. The low I-p (from 5.00 to 5.21 eV) of the materials enables efficient hole-injection from the hole-transporting layer and results in low turn-on (<2.7 V) and operation voltages (<5.5 V to give 1000 cd m(-2)).
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