期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 21, 期 20, 页码 7161-7165出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1jm10282f
关键词
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资金
- National Key Project on Basic Research of China [2009CB930104]
- Zhejiang Provincial Natural Science Foundation of China [R2080061]
- Chinese Universities Scientific Fund [2010QNA3009]
- Qianjiang Talent Program of Zhejiang Province, China [2009R10013]
Photo-luminescent nanofibrous crystalline silicon with hierarchical cross-linked network structures was obtained by low-temperature magnesiothermic reduction of nano-precise silica replica of natural cellulose substance (e.g., commercial filter paper and cotton). Ultrathin silica films were deposited onto the individual nanofibres of cellulose substance by surface sol-gel process, and successive calcination of the silica/cellulose composite gave nano-precise silica replica of the initial cellulose substance; further reduction of the silica matter at 670 degrees C resulted in bulk nanofibrous silicon material which was composed of crystalline silicon nanofibres replicated strictly from the original cellulose nanofibres. The resulting porous nanofibrous structured silicon material possesses strong blue or red photoluminescence when excited with ultraviolet or green light.
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