期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 21, 期 27, 页码 10069-10076出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1jm10710k
关键词
-
We report the electrochemical study of TiSnSb towards Li, as a negative electrode for Li-ion batteries. TiSnSb can reversibly take up more than 5 lithiums per formula unit leading to reversible capacities of 540 mA h g(-1) and 4070 mA h cm(-3) at 2 C rate. From complementary operando XRD and Mossbauer spectroscopy measurements, it was shown that during the first discharge the TiSnSb undergoes a conversion process leading simultaneously to the formation of Li-Sb and Li-Sn alloys. At the end of the discharge, Li3Sb and Li7Sn2 were identified. Once the first discharge is achieved, both phases were shown to form Ti-Sn or Ti-Sb or Ti-Sn-Sb nanocomposites. The cycling performance of TiSnSb was shown to be excellent with maintaining 90% of the specific capacity during 60 cycles at 2 C rate. The good electrochemical performance of TiSnSb (compared to Sn and Sb) seems to be a consequence of the presence of the non-active metal. The comparative study of Ti/Sn/Sb composite demonstrated that the structural feature of the pristine material clearly impacts both the mechanism involved during the cycling and the corresponding performance.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据