期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 21, 期 24, 页码 8694-8699出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1jm10774g
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Hollow boron nitride nano-polyhedrons have been successfully prepared by annealing of boron nitride nanoparticles in a nitrogen atmosphere at 1800 degrees C without a catalyst. In our two-step process, we demonstrated that these boron nitride nanoparticles prepared by spray-pyrolysis of borazine are key precursors to grow these architectures. The samples were carefully analyzed using electron microscopies and Energy-Dispersive X-ray spectroscopy analysis. Based on such characterization tools, the growth mechanism of these architectures has been discussed and detailed. It is noteworthy that these nanostructures are generated via a solid-state transformation in relatively high yields without a metal catalyst and might open new opportunities in exploring chemical and physical properties.
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