期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 21, 期 5, 页码 1462-1469出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0jm02293d
关键词
-
资金
- EPSRC
- JCEMolChem
- EPSRC [EP/E036244/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/E036244/1] Funding Source: researchfish
A hybrid tetrathiafulvalene-oligothiophene compound has been synthesised, in which the fulvalene unit is fused on both sides to an end-capped septithiophene oligomer. The compound (1) has been studied by cyclic voltammetry, UV-vis spectroelectrochemistry and X-ray crystallography. The properties of this material are compared to the half-unit (9), which lacks the TTF core and contains only one septithiophene chain. In the case of the larger molecule, there are multiple and complex redox processes leading to the loss of 6-8 electrons per molecule. Charge generation layer time-of-flight measurements give maximum hole mobilities of ca. 1 x 10(-5) cm(2) V-1 s(-1).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据