期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 21, 期 16, 页码 6027-6033出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0jm04344c
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资金
- National Natural Science Foundation of China [21074034]
- Ministry of Education of China [309013]
- Fundamental Research Funds for the Central Universities
- Shanghai Municipal Educational Commission [08GG10]
- Shanghai Eastern Scholarship
Bistable electrical conductivity switching and non-volatile memory effects were demonstrated in Al/polymer/indium-tin oxide sandwich structure devices, constructed from two poly(N-vinylcarbazole) derivatives with pendant azobenzene chromophores and terminal electron acceptor moieties (-NO(2) or -CN). Both polymers (PVK-AZO-NO(2) and PVK-AZO-2CN) exhibit write-once read-many-times (WORM) type memory effects, with low switching threshold voltages below -2 V and high ON/OFF current ratios of similar to 10(5)-10(6). The observed electrical bistability in both polymers can be attributed to the field-induced charge transfer interaction between carbazole electron donor and terminal electron acceptor (-NO(2) or -CN) moieties, and subsequent charge trapping at the intermediate azobenzene chromophores. The proposed switching mechanism is supported by the changes in the UV-visible absorption spectra of the polymer film upon transition from the OFF to the ON state.
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