期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 20, 期 7, 页码 1253-1260出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b916612b
关键词
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资金
- Ministry of Education, Sciences, Sports, and Culture, Japan [21655054, 21111522]
- PRESTO, JST, Japan
Formation of hierarchically self-organized architectures in organic media and their non-wetting surface features of a series of fullerene-C(60) derivatives bearing different numbers of long hydrocarbon chains (1-3) and semiperfluoro-alkyl tails (4) are investigated by means of a variety of techniques, including X-ray diffraction, differential scanning calorimetry, as well as spectroscopic and microscopic methods. All derivatives self-assemble into a bilayer arrangement with their fundamental structural subunit and lamellar distance ranging from 2.88 to 4.85 nm depending on the substituents. The hydrocarbon-C(60) derivatives (1-3) provide well-defined three-dimensional microparticles having a nanoflaked outer surface morphology or microparticles composed of many plate-like units in 1,4-dioxane solution, both architectures enhancing the surface water-repellency. The microparticles with a nanoflaked-outer surface obtained from a C(60) derivative with semiperfluoro-alkyl chains (4) in a diethoxyethane solution exhibit a surface water-repellency comparable to objects formed from the hydrocarbon-hybrid C(60) derivatives. Taking into account the moderate hydrophobic nature of the C(60) surface compared to the high hydrophobicity of the hydro-or fluoro-carbons, these results suggest that the C(60) moieties are exposed to the outer surface in the supramolecular objects formed in polar solvent conditions and define their non-wetting properties.
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