期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 20, 期 42, 页码 9476-9483出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0jm01722a
关键词
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资金
- EU (MolSpinQIP)
- ERC
- Spanish Ministerio de Ciencia e Innovacion
- FEDER [CSD2007-00010, MAT2007-61584, CTQ-2008-06720]
- Generalitat Valenciana
Here we report the intercalation of a Mn-II-Cr-III oxalate-bridged extended network into the interlamellar space offered by a Zn-II-Al-III LDH host. This material exhibits ferrimagnetic ordering below 3 K from dominant antiferromagnetic interactions between metallic centres through the oxalate linker. Our result opens the door for the design of a completely new sort of hybrid magnetic multilayers from molecule-based magnets and layered inorganic flexible hosts, where the intrinsic properties of both sub-layers can be combined.
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