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TUD-1: synthesis and application of a versatile catalyst, carrier, material ...

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JOURNAL OF MATERIALS CHEMISTRY
卷 20, 期 4, 页码 642-658

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ROYAL SOC CHEMISTRY
DOI: 10.1039/b904193a

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  1. NWO (Mozaik fellowship)

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The three-dimensional sponge-like mesoporous material TUD-1 is straightforward to prepare. Its synthesis can readily be modified to introduce metals into the framework of TUD-1, imparting many different catalytic activities. M-TUD-1 catalysts have proven to be very active, unlimited by diffusion and very stable. By combining two metals into one TUD-1 catalyst, synergy between Lewis and Bronsted acid sites could be induced; incorporation of zeolites similarly gave rise to synergy. In addition to successful applications in redox-, acid- and photo-catalysis TUD-1 proved to be an excellent carrier material for catalysts, enabling new applications. TUD-1 was used as a contrast agent and drug delivery system, indicating that this material is but at the beginning of its potential applications.

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