4.3 Article

An efficient composite hybrid catalyst fashioned from Pt nanoparticles and Sb-doped SnO2 nanowires for alcohol electro-oxidation

期刊

JOURNAL OF MATERIALS CHEMISTRY
卷 20, 期 36, 页码 7859-7863

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0jm01507e

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资金

  1. Program for Intergrated Molecular Systems (PIMS/GIST)
  2. Korea Science and Engineering Foundation [20090058918]
  3. National Research Foundation of Korea [R15-2008-006-03002-0]
  4. Technology and New & Renewable Energy R&D program in the Republic of Korea [20093020030020-11-1-000]

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We report the development of a hybrid catalyst composed of Sb-doped SnO2 nanowires (ATO NWs) with Pt/C that shows greatly increased catalytic activity of approximately 80% and 50% higher than Pt/C alone for ethanol and methanol electro-oxidation, respectively. The enhanced catalytic performances of the hybrid catalyst system is attributed to improved charge transport properties from 1-D semiconducting ATO NWs on the oxidation electrode. Furthermore, our hybrid catalyst has much higher stability for alcohol oxidation due to the ATO NWs.

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