期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 20, 期 36, 页码 7599-7605出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0jm00872a
关键词
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资金
- Herchel Smith fund
Mechanochemical synthesis is experiencing a dynamic re-discovery in the areas of organic and metal-organic materials. Emerging mechanochemical methods, such as liquid-assisted grinding (LAG) or ion-and liquid-assisted grinding (ILAG) achieve enhanced molecular mobility through the addition of near-stoichiometric amounts of a liquid phase to a solid-state reaction, and are aided by catalytic and templating effects. This article highlights the exciting areas of application for these mild mechanochemical methods: one-pot assembly of soft'' metal-organic and organic materials, and the rapid room-temperature synthesis of porous metal-organic frameworks directly from a metal oxide.
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