期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 20, 期 1, 页码 123-134出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b915940a
关键词
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资金
- DARPA [N00014-06-1-0897]
- Office of Naval Research [N00014-08-1-0928]
- AFOSR [FA9550-09-1-0320]
- National Science Foundation [DMR0120967]
- NSF [ECS03- 35765]
A series of highly soluble donor-acceptor (D-A) copolymers containing N-(3,4,5-tri-n-decyloxyphenyl)-dithieno[3,2-b:2',3'-d]pyrrole (DTP) or N-(2-decyltetradecyl)-dithieno[3,2-b:2',3'-d] pyrrole (DTP') as donor and three different acceptors, 4,7-dithien-2-yl-[2,1,3]-benzothiadiazole, 4,9-dithien-2-yl-6,7-di-n-hexyl-[1,2,5]thiadiazolo[3,4-g]quinoxaline and 4,8-dithien-2-yl-2 lambda(4)delta(2)-benzo[1,2-c;4,5-c']bis[1,2,5]thiadiazole (BThX, X = BTD, TQHx(2), BBT, respectively) were synthesized by Stille coupling polymerizations. The optical and electrochemical properties of these copolymers were investigated, along with their use in field-effect transistors and photovoltaic devices. The band gaps (eV) estimated from UV-vis-NIR spectra and electrochemical measurements of the copolymers varied from ca. 1.5-0.5 eV, and were consistent with quantum-chemical estimates extrapolated using density functional theory. Oxidative and reductive spectroelectrochemistry of the copolymers indicated they can be both p-doped and n-doped, and three to four differently colored redox states of the polymers can be accessed through electrochemical oxidation or reduction. The DTP-BThBTD and DTP-BThTQHx(2) copolymers exhibited average field-effect hole mobilities of 1.2 x 10(-4) and 2.2 x 10(-3) cm(2)/(Vs), respectively. DTP-BThBBT exhibited ambipolar field-effect characteristics and showed hole and electron mobilities of 1.2 x 10(-3) and 5.8 x 10(-4) cm(2)/(Vs), respectively. Bulk heterojunction photovoltaic devices made from blends of the copolymers with 3'-phenyl-3'H-cyclopropa[1,9](C-60-I-h)[5,6]fullerene-3'-butanoic acid methyl ester (PCBM) (1:3 weight ratio) exhibited average power conversion efficiencies as high as 1.3% under simulated irradiance of 75 mW/cm(2).
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