期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 19, 期 39, 页码 7178-7190出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b903929p
关键词
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资金
- Korea Science and Engineering Foundation (KOSEF) [R11-2005-00800000-0]
- Korea Research Foundation [KRF2004-005-C00093]
[Re(6)Q(8)L(6)](4-) (Q S, Se, Te) clusters can serve as promising building blocks'' for the creation of new porous framworks, nanoparticles and mesoporous materials. Since [Re(6)Q(8)L(6)](4-) clusters have multi-anchoring sites for transition metals, metal-organic complexes, polymers, and multidentated metal complexes, they could be assembled to form various inorganic or organic-inorganic hybrid solids with new various spatial and chemical functions. Because of the controllable architectures and multi-anchoring sites of clusters together with their photoluminescence, rhenium cluster complexes are promising potential candidates as catalysts, chemical color sensors, magnetic materials, gas storage materials, optoelectronic, diagnostic agents, and gene/drug carriers. A new type of mesoscale material comprising [Re(6)Q(8)(CN)(6)](4-) and various divalent transition metals in the presence of a liquid crystal template are obtained in 3D cubic, 2D hexagonal, and lamellar phases. The hexahydroxo complexes [Re(6)Q(8)(OH)(6)](4-) (Q S, Se) with high reactivities and a unique rhenium sulfido-cyanide compound, K-8[Re12CS17(CN)(6)] with a C-centered {Re-12} cluster unit were discovered and still many more new rhenium metal cluster complexes at various reaction conditions remain to be explored.
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