期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 19, 期 23, 页码 3793-3818出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b808795b
关键词
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资金
- Ministerio de Educacion y Ciencia [MAT2007-60400, MAT2007/66737-C02-01]
- Gobierno Vasco (Ayudas para apoyar las actividades de Grupos de Investigacion del Sistema Universitario Vasco) [IT-177-07, IT-312-07]
Here we present a summary of the work carried out in the last few years on the synthesis and characterization of a new type of organically templated inorganic-organic solid based on the (HPO3)(2-) phosphite oxoanion, with special focus on the magnetostructural properties of those systems containing open d-shell transition metal ions. As a result of the inherent connectivity of the metal-phosphite framework, the magnetic behaviour of the great majority of these materials is characterized by weak antiferromagnetic interactions that become relevant only at low temperature.
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