期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 18, 期 13, 页码 1427-1439出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b717958h
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Recent development of artificial photosynthetic systems using photofunctional nanomaterials composed of multiporphyrins and carbon-based pi-electron acceptors such as fullerenes, carbon nanotubes and a new type of nanocarbon is reviewed by focusing on their photoinduced electron-transfer properties. Electron donor-acceptor ensembles composed of porphyrins and fullerenes are described, covering small electron donor-acceptor dyads to larger multi-component systems including porphyrin-based photofunctional nanometerials. Such photofunctional nanomaterials composed of multiporphyrins and carbon-based pi-electron acceptors (in particular C-60) have been utilized to construct efficient light energy conversion systems such as photovoltaic devices.
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