Effect of the organic moiety nature on the synthesis of hierarchical ZSM-5 from silanized protozeolitic units

The synthesis of hierarchical ZSM-5 from silanized protozeolitic units has been accomplished following a three step procedure comprising gel precrystallization at 90 degrees C, grafting of the seed silanization agent (SSA) and hydrothermal crystallization at 170 degrees C. The following four organosilanes were tested and investigated as SSAs: 3-aminopropyltrimethoxysilane (APTMS), isobutyltriethoxysilane (IBTES), phenylaminopropyltrimethoxysilane (PHAPTMS) and octadecyltrimethoxysilane (ODTMS). The last agent became anchored to the zeolite seeds to a rather reduced extent (1.3%) and the obtained material presented properties very similar to those of a reference nanocrystalline ZSM-5 (Sext similar to 100 m(2) g(-1), S(BET) similar to 450 m(2) g(-1), crystallite size 20-80 nm). In contrast, silanization of the protozeolitic units with APTMS or IBTES led to ZSM-5 samples having large surface areas (Sext similar to 200 m(2) g(-1), SBET similar to 500 m(2) g(-1)) and exhibiting mesopores (D(p) similar to 8 nm). These materials are formed by 300 -400 nm particles consisting of aggregates of ZSM-5 nanounits (10 -20 nm). Seed silanization with PHAPTMS caused the greatest enhancement in surface area (S(BET) 573 m(2) g(-1), S(ext) 225 m(2) g(-1)), the material so obtained being formed by the smallest nanounits (5 -10 nm) within the aggregates. Moreover, this sample presented a hierarchical porosity with pores around 2.0 -3.0 nm in addition to those generated by the MFI channels. The strong changes induced in the ZSM-5 crystal size and properties when using PHAPTMS as SSA have been attributed to this agent being very effective in both anchoring onto the protozeolitic units and perturbing the subsequent crystal growth step.