期刊
JOURNAL OF MASS SPECTROMETRY
卷 46, 期 7, 页码 712-719出版社
WILEY
DOI: 10.1002/jms.1957
关键词
MALDI-TOFMS; coordination compound; organometallic; metal complex; nanomaterials; metallodrugs
资金
- Engineering and Physical Sciences Research Council (EPSRC) [EP/F014341/1]
- EPSRC [EP/F014341/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/F014341/1] Funding Source: researchfish
A mini-review of the characterisation of metal-containing compounds by matrix-assisted laser desorption/ionisation time-of-flight mass spectrometry (MALDI-TOFMS) is presented. Organometallic and coordination compounds have many varied applications, most notably in industrial catalytic processes and also in the electronics and healthcare sectors. In general, the compounds discussed, be they small or large molecules, have a high percentage metal content, rather than simply containing 'a metal atom'. A brief history of the field is given, but the main scope over the last 5 years is covered in some detail. How MALDI-TOFMS compliments electrospray for metal-containing compounds is highlighted. Perspectives on recent advances, such as solvent-free and air/moisture-sensitive sample preparation, and potential future challenges and developments, such as nanomaterials and metallodrug/metallometabolite imaging, are given. Copyright (C) 2011 John Wiley & Sons, Ltd.
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