期刊
JOURNAL OF MASS SPECTROMETRY
卷 45, 期 12, 页码 1443-1451出版社
WILEY-BLACKWELL
DOI: 10.1002/jms.1860
关键词
corroles; mass spectrometry; photochemistry; electrospray ionization; field desorption; photoionization
资金
- Polish Ministry of Science and Higher Education [N N204 263837]
Corroles, ring-contracted analogs of porphyrins, are an important class of compounds which have attracted the attention of many researchers in the fields of organic, coordination and physical chemistry. In the present work, the stability and the decomposition pathways of a diverse set of meso-substituted corroles have been studied using mass spectrometry (MS), UV-Vis absorption and preparative methods combined with NMR spectroscopy. Four different ionization methods (electrospray ionization, field desorption, atmospheric pressure photoionization and atmospheric pressure chemical ionization) were utilized to investigate light- and oxygen-induced decomposition in various solvents. It was found that the rate of decomposition in MeCN is significantly higher than in CH2Cl2, hexane, MeOH and ethyl acetate. HR-MS combined with CID-MS/MS enabled us to identify the products of initial decomposition. Surprisingly, numerous smaller open-chain compounds were also detected. Large-scale decomposition of a corrole bearing sterically hindered substituents at positions 5 and 15 allowed us to isolate mg quantities of three decomposition products: isocorrole and isomeric biliverdin-type species. These are formed as a result of oxygen attack on the meso-10 position. Copyright (c) 2010 John Wiley & Sons, Ltd.
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