期刊
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
卷 323, 期 16, 页码 2109-2114出版社
ELSEVIER
DOI: 10.1016/j.jmmm.2011.02.018
关键词
Zinc ferrite; Magnetic fibers; Electrospinning; Poly(vinyl) alcohol; Calcination
资金
- DOE [DE-FG02-08ER46526]
- National Center on Minority Health and Health Disparities [P20MD001112]
Magnetic nanofibers of ZnFe2O4/gamma-Fe2O3 composite were synthesized by electrospinning from a sol-gel solution containing a molar ratio (Fe/Zn) of 3. The effects of the calcination temperature on phase composition, particle size and magnetic properties have been investigated. Zinc ferrite fibers were obtained by calcinating the electrospun fibers in air from 300 to 800 degrees C and characterized by thermogravimetric analyses, Fourier transformed infrared spectroscopy, X-ray photoemission spectroscopy, X-ray diffraction, vibration sample magnetometry and magnetic force microscopy. The resulting fibers, with diameters ranging from 90 to 150 nm, were ferrimagnetic with high saturation magnetization as compared to bulk. An increase in the calcination temperature resulted in an increase in particle size and saturation magnetization. The observed increase in saturation magnetization was most likely due to the formation and growth of ZnFe2O4/gamma-Fe2O3 diphase crystals. The highest saturation magnetization (45 emu/g) was obtained for fibers calcined at 800 degrees C. (C) 2011 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据