期刊
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
卷 320, 期 6, 页码 898-905出版社
ELSEVIER
DOI: 10.1016/j.jmmm.2007.09.015
关键词
molecular nanomagnet; magnetic anisotropy; spin fluctuation; Mossbauer; ROHF calculation
The magnetic anisotropy and the spin fluctuations of the paramagnetic molecule [Fe(OMe)(ddpm)(2)](2) are analyzed by means of Mossbauer spectroscopy in the temperature range [7.6 - 33] K. Spectra in the presence of a 5T magnetic field directed along the gamma rays were collected, by using a sample of pseudo-single crystal prepared by oriented grains. From the fits of the spectra, the hyperfine parameters are determined. Fits give also the value and direction of the magnetic anisotropy, referred to the electric field gradient (EFG) principal axes. The latter, together with the EFG components, were evaluated by means of ROHF ab initio calculations. Lastly, the rate of the spin transitions in function of T is discussed. (C) 2007 Elsevier B. V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据