On the practical aspects of recording wideline QCPMG NMR spectra

The practical aspects of applying CPMG for acquisition of wideline powder patterns are examined. it is shown that most distortions/modulations of spikelet spectra can be traced to the incoherent signal averaging from multiple coherence transfer pathways. A strategy for minimizing these distortions/modulations is described. Also, a few interesting observations regarding the implementation of the wideline WURST-QCPMG experiment are presented, namely the accumulation of second-order signal phase and the effects of varying the sweep rate and rf field of chirp pulses. (C) 2010 Elsevier Inc. All rights reserved.