Study of Salinity and pH Effects on Gelation Time of a Polymer Gel Using Central Composite Design Method

Experiments were conducted to investigate the main effects of salinity (NaCl) concentralions and pH factors and their interactions on the gelation time response of a polymer gel used in a water shutoff system in oil field reservoirs. Central composite design (CCD) was used to design experiments and a mathematical model building. The main advantage of CCD was to generate the quadratic mathematical model for the gelation time as functions of salinity and pH factors. Tests were limited and optimized by CCD points including low star (axial), low factorial, central, high factorial, and high star points. The evaluation of the data and the developed model were performed through the examination of graphical trend of residuals and a numerical approach. Analysis of variance (ANOVA) was used to estimate the amount of data variations from the model predictions. It was found that the model was significant at the 99% confidence against test data. The results showed that the gelation time was dependent more on pH than salinity. For low pH, the gelation time increased with increasing of the salinity, while for a high pH (>4) the relationship was inversed. The research shows that CCD can effectively be applied for the modeling of gelation time and finding an optimum condition to achieve maximum or minimum gelation time for different salinity and pH factors.