期刊
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY
卷 47, 期 3, 页码 248-253出版社
TAYLOR & FRANCIS INC
DOI: 10.1080/10601320903527061
关键词
Polyphenylquinoxaline; solubility; thermal stability; refractive index
New polyphenylquinoxalines (PPQs) containing methyl substituents have been synthesized and characterized. The PPQs were prepared by the polycondensation of a newly-developed aromatic tetraketone, 4,4' -bis(4-benzilyloxy)-3,3',5,5' -tetramethylbiphenyl (III) and aromatic tetraamines. Compared with the non-methyl-substituted PPQs derived from 1,4-bis (4-benzilyloxy)benzene (I) and 4,4' -bis(4-benzilyloxy)biphenyl (II), the obtained polymers exhibited better solubility. They were soluble not only in the common m-cresol and chloroform, but in polar aprotic solvent N-methyl-2-pyrrolidinone (NMP). The polymers showed glass transition temperatures of 325 degrees C for PPQ-IIIa (from III and 3,3',4,4' -tetraaminobiphenyl) and 287 degrees C for PPQ-IIIb (from III and 3,3',4,4' -tetraaminodiphenyl ether), which were much higher than their analogues. The PPQs exhibited good thermal stability up to 470 degrees C in nitrogen and good optical transparency at 450 nm with a thickness of around 10 m. The refractive indices and birefringences of the PPQs were in the range of 1.6998-1.7739 and 0.0002-0.0007, respectively.
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