期刊
JOURNAL OF LUMINESCENCE
卷 204, 期 -, 页码 589-597出版社
ELSEVIER
DOI: 10.1016/j.jlumin.2018.08.071
关键词
Up-conversion luminescent properties; ZAGO:Yb,Er; Blue, green and red emission; 980 nm excitation
类别
资金
- National Natural Science Foundation of China [81171463]
Al3+ doped ZnGa2O4:Yb3+, Er3+ powder phosphors with different Al3+ doping content were synthesized by solid-state method with subsequent thermal treatment at 1300 degrees C. The morphology, structural characterization and up-conversion luminescent properties of as-prepared samples were investigated by scanning electron microscope (SEM), x-ray diffraction (XRD) and LSP920 spectrofluorometer under the excitation of a 980 nm laser with different power density. In brief, all samples have good crystallinity and consist of long rods with width of 600-900 nm and length of 1-3 mu m. Under the 980 nm excitation, all phosphors can generate strong green emission at 524 nm, 549 nm (attributed to H-2(11/2) -> I-4(15/2) transition, S-4(3/2) -> I-4(15/2) transition of Er3+), red emission at 659 nm (corresponding to F-4(9/2) -> I-4(15/2) transition of Er3+) and slight blue emission at 410 nm (attributed to H-2(9/2) -> I-4(15/2) transition of Er3+). By contrast, the up-conversion efficiency and intensity raises with the doping of Al3+ ions. Accordingly, the doping of Al3+ ions has no effect on up-conversion emission peaks, but improve the up-conversion efficiency and intensity of phosphors.
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