期刊
JOURNAL OF LUMINESCENCE
卷 131, 期 1, 页码 147-154出版社
ELSEVIER
DOI: 10.1016/j.jlumin.2010.09.041
关键词
Photophysics; Solvatochromism; Fluorescence; Polarity; Dipole-dipole interaction
类别
资金
- CSIR, New Delhi [01(2261)/08/EMR-II]
- UGC, Government of India
Photophysical modulations of three indoloquinoline derivatives viz 5-Methyl-5H-indolo[3 2-c]quinoline (MIQ) 8-Chloro-5-methyl-5H-indolo[3 2-c]quinoline (CMIQ) and 2,8-Dichloro-5-methyl-5H-indolo[3 2-c]quinoline (DCMIQ) have been studied These compounds belong to the cryptosanguinolentine family and are known to have potential anti-cancer abilities In the present work we studied the effect of solvent polarity on introduction of one or two chloro (-Cl) group/s at chosen sites on the parent cryptosanguinolentine The compounds exist mainly in two forms neutral and zwitterionic in equilibrium at ground state Interestingly all the three compounds exhibit hypsochromic shift in their absorption and fluorescence spectra with increase in relative permittivity of solvents in most of the cases Blue-shift in fluoroscence might be due to lesser dipole moment of the species in the excited state Time-resolved fluorescence spectroscopy clearly indicates the presence of two species in all the solvents in the excited state (except MIQ in water) The shift in the molecular polarity with chloro substitution/s seems to be responsible for the contributions of the two species in the excited state The relative contributions are found to alter remarkably in a regular manner when MIQ is compared with CMIQ and DCMIQ This behavior is supposed to be mainly due to dipole-dipole interaction between the solvent molecules and the fluorophores (C) 2010 Elsevier B V All rights reserved
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