Investigation of the influence of silver and tin on the luminescence of trivalent europium ions in glass

Europium-doped aluminophosphate glasses prepared by the melt-quenching technique have been studied by photoluminescence (PL) and X-ray photoelectron spectroscopy (XPS). The effects of silver and tin doping, and of further thermal processing on Eu3+ ions luminescence have been assessed. For the glass system containing only europium, Eu3+ PL observed under UV excitation is suggested to occur through energy transfer from the excited glass host. After silver and tin doping, an enhanced UV excited Eu3+ PL has been indicated to occur essentially due to radiative energy transfer from isolated Ag+ ions and/or two fold-coordinated Sn centers. Since thermal processing of the material leads to a quenching effect on Eu3+ PL and Ag nanoparticles (NPs) formation due to reduction of silver ions by tin, XPS was employed in order to investigate the possibility for Eu3+ -> Eu2+ reduction during HT as a potential source of the PL decrease. The data points towards Ag NPs as main responsible for the observed weakening of Eu3+ PL (C) 2009 Elsevier B.V. All rights reserved.