期刊
JOURNAL OF LUMINESCENCE
卷 128, 期 8, 页码 1271-1284出版社
ELSEVIER
DOI: 10.1016/j.jlumin.2007.12.041
关键词
terbium; spectroscopy; magentic susceptibility; crystal field analysis
类别
Detailed analyses of spectroscopic and temperature-dependent magnetic susceptibility data are reported for the crystal-field split energy levels of the F-7(J) and D-5(4) of Tb3+ in stoichiometric single crystals of ortho-aluminate TbAlO3. The spectroscopic data include absorption spectra obtained between 2940 and 480 nm from 8 to 300 K. High resolution fluorescence spectra are reported, representing transitions from D-5(4) to F-7(6,5,4,) at a sample temperature of 85 K. Using crystal-field modeling techniques recently adapted for low symmetry systems, we have assigned all 58 experimental Stark levels within the F-7(J) and D-5(4) manifolds, with a fitting standard deviation of 4.5 cm(-1) (3.8 cm(-1) rms error). As a further test, the theoretical Stark levels and calculated wavefunctions were used to determine the temperature dependence of the magnetic susceptibility along the c-axis of the TbAlO3 crystal. Good agreement is obtained between the calculated susceptibility and temperature-dependent magnetic data reported earlier, including a prediction of a 0.2 cm(-1) splitting of the ground-state quasi-doublet. The susceptibility calculation also confirms the predicted ordering of states within the F-7(6) multiplet manifold. (c) 2007 Elsevier B.V. All rights reserved.
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