期刊
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
卷 22, 期 4, 页码 897-902出版社
SPRINGER
DOI: 10.1007/s10904-012-9664-1
关键词
Coordination polymer of Ag(I); Thiodiglycolic acid; Ag-Ag bond; Photoluminescence
资金
- UGC, New Delhi, India [39-1027/2010 (SR)]
- UGC
Reaction of thiodiglycolic acid and silver nitrate under ultrasonic condition forms a 3D supramolecular framework of silver with composition [Ag-2(tdga)] (n) (1). X-ray single crystal structure analysis reveals repetition of paddle wheel units in the network. A weak Ag-Ag bond is present in the complex. A new mu(8)-coordination mode of the thiodiglycolate ligand is identified. Photoluminescence and thermal characterization of the complex was examined. Novel 3D silver coordination polymer with Ag-Ag bond is synthesized using thiodiglycolic acid ligand and characterized by X-ray diffraction, IR, photoluminescence and TG analysis. The ligand displays a unique type of coordination.
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