期刊
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
卷 22, 期 2, 页码 301-306出版社
SPRINGER
DOI: 10.1007/s10904-012-9665-0
关键词
Polyoxometalate; Assembly; Composite material; Vesicle
资金
- NSFC [20625307, 21103071]
- Natural Science Foundation of Shandong Province, China [ZR2011BQ016]
- National Basic Research Program of China (973 Program) [2009CB930103]
This paper is a review the polyoxometalate-based composite materials, including polyoxometalate incorporated Langmuir and Langmuir-Blodgett, layer-by-layer multilayers and novel honeycomb films, self-assembly structures of modified polyoxometalate complexes (e.g., onion-like structures, new inorganic-organic-inorganic vesicles, thermotropic and lyotropic liquid crystalline structures, gels), and amino acid- and protein-polyoxometalate nanorods and nanoparticles. Polyoxometalate-embedded layer-by-layer multilayer films show electrocatalytic or photochemical activity; and, novel photoluminescent honeycomb films templated by microwater droplets are reviewed. Inorganic-organic-inorganic hybrid vesicles display the potential as nano-switches. In addition, amino acid- and protein-polyoxometalate composite nanostructures indicate potential antimicrobial applications. Therefore, the polyoxometalate-based composite materials have promising applications in electrochemistry, photochemistry and biomedicine.
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