期刊
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
卷 18, 期 2, 页码 300-303出版社
SPRINGER
DOI: 10.1007/s10904-008-9201-4
关键词
crystal structure; copper(I); phosphine; naphthyridine; halogen-halogen bond
The copper(I) complex [Cu(DPPEO)(L-1)Cl] center dot CH3CN (1) (DPPEO = 1,2-bis(diphenylphosphino)ethane monoxide; L-1 = 5,7-dimethyl-2-chloronaphthyridine) was prepared by reacting L-1 with CuCl in the presence of DPPE. The compound has been characterized by X-ray diffraction analysis. Compound 1 is a tri-coordinated mononuclear complex, which forms one-dimensional chain through intermolecular halogen-halogen bonds.
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