Transesterification of waste cooking palm oil by MnZr with supported alumina as a potential heterogeneous catalyst

The transesterification of waste cooking palm oil (WCPO) with methanol into fatty acid methyl esters (FAMEs) was investigated using solid acidic mixed oxide catalysts Mn3.5xZr0.5yAlxO3 prepared via coprecipitation. The effects of reaction temperature, time, molar methanol-to-oil ratio, and catalyst loading were investigated. The stability of the catalytic activity was examined via leaching and reusability tests through five consecutive batch runs. The catalyst achieved a FAME content of more than 93%, and the optimal reaction conditions are as follows: reaction temperature of 150 degrees C, reaction time of 5 h, molar methanol-to-WCPO ratio of 14:1, and catalyst loading of 2.5 wt.%. (C) 2014 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.