期刊
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
卷 18, 期 1, 页码 174-177出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2011.11.020
关键词
5-Hydroxymethylfurfural (HMF); 2,5-Dihydroxymethylfuran (DHMF); 5-Hydroxymethylfuranoic acid (HMFA); Ionic liquid; Cannizzaro reaction
资金
- Ministry of Knowledge Economy, Republic of Korea
- Research Center for Energy Conversion and Storage, Agency for Defense Development, Honam Petrochemicals
- Samsung Electronics
2,5-Dihydroxymethylfuran (DHMF) and 5-hydroxymethylfuranoic acid (HMFA) are the versatile intermediate chemicals of high industrial potential. An efficient preparation of both DHMF and HMFA is reported from biomass-derived HMF via a Cannizzaro reaction using ionic liquids as a reusable reaction solvent under the water-free conditions. The operationally simple and environment-friendly process produces both DHMF and HMFA from HMF consistently in good to high yields up to five runs with the recycled ionic liquid. (C) 2011 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
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