期刊
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
卷 17, 期 3, 页码 377-381出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2011.05.008
关键词
Biomass; Glycerol; Acetalisation; Solketal; Promoted zirconia catalysts
资金
- Council of Scientific and Industrial Research, New Delhi
Acetalisation of biomass derived glycerol was performed with acetone over zirconia and promoted zirconia catalysts to synthesize solketal. The catalytic experiments were carried out at room temperature. It was observed that the promoted zirconia catalysts exhibit promising catalytic activity. The activity increased in the order of ZrO(2) < WO(x)/ZrO(2) < MoO(x)/ZrO(2) < SO(4)(2-)/ZrO(2). All catalysts exhibited an excellent selectivity of similar to 97% towards solketal. The effect of different parameters, such as molar ratio of acetone to glycerol, catalyst wt.% and time-on-stream was studied over zirconia and promoted zirconia catalysts. The synthesized catalysts were characterized by XRD, BET surface area, ammonia-TPD and FT-Raman techniques. Characterization results revealed that the addition of promoters strongly influences the surface acidity of ZrO(2) and enhances the tetragonal zirconia phase. (C) 2011 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
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