期刊
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
卷 76, 期 1-2, 页码 223-230出版社
SPRINGER
DOI: 10.1007/s10847-012-0194-9
关键词
Melamine; Salen; Salophen; Schiff bases; Co-polymers; Polymer complexes
In this study, new polymer Fe(III) and Cr(III) complexes were synthesized. These polymer complexes were characterized by using elemental analysis, FT-IR spectroscopy, MS, thermal analyses and magnetic susceptibility measurement technics. Their thermal degradations were investigated, and co-polymerization was compared to aliphatic polymerization by using 1,2-dibromomethylbenzene and o-phenylenedialdehyde. Finally, metal ratios of the complexes were determined by using atomic absorption spectroscopy. The complexes are distorted octahedral low-spin (S = 1/2) Fe(III) and distorted octahedral (S = 3/2) Cr(III) bridged by COO- and catechol groups.
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