期刊
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
卷 68, 期 1-2, 页码 165-173出版社
SPRINGER
DOI: 10.1007/s10847-010-9762-z
关键词
Melamine; Salen; Salophen; Schiff bases; Catechol
资金
- Selcuk University [2005/5201005]
In this study, firstly, two single substitute novel ligands have been synthesized by reacting melamine with 3,4,-dihydroxybenzaldeyhde or 4-carboxybenzaldehyde. Then, eight new mono nuclear single substitute [Salen/Salophen Fe(III) and Cr(III)] complexes have been synthesized by reacting the ligands [2-(3,4-dihydroxybenzimino)-4,6-diamimo-1,3,5-triazine and 2-(4-carboxybenzimino)-4,6-diamimo-1,3,5-triazine)] with tetradentate Schiff bases N,N'-bis(salicylidene)ethylenediamine-(salenH(2)) or bis(salicylidene)-o-phenylenediamine-(salophen H-2). And then, all ligands and complexes have been characterized by means of elementel analysis, FT-IR spectroscopy, H-1 NMR, LC-MS, thermal analyses and magnetic suscebtibility measurements. Finally, metal ratios of the prepared complexes were determined using AAS. The complexes have also been characterized as disorted octahedral low-spin Fe(III) and Cr(III) bridged by catechol and COO- groups.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据