期刊
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
卷 67, 期 1-2, 页码 13-18出版社
SPRINGER
DOI: 10.1007/s10847-009-9662-2
关键词
Clathrate hydrate; Tetrabutylammonium polyacrylates; Noble gas; High pressure; Phase diagram
资金
- Presidium of SB RAS [62]
Temperatures of hydrate decomposition were measured by means of the differential thermal analysis at a pressures up to 800-900 Mpa in the systems: cross-linked tetrabutylammonium polyacrylate-water and cross-linked tetrabutylammonium polyacrylate-water-noble gas (He, Ne, Ar, Kr, Xe). The effect of the deformation of D- cavities of the hydrates on the temperature of their decomposition is discussed on the basis of the experimental data.
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