4.5 Article

β-Diketiminato Organolead Complexes: Structures, 207Pb NMR, and Hammett Correlations

期刊

ORGANOMETALLICS
卷 34, 期 11, 页码 2515-2521

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AMER CHEMICAL SOC
DOI: 10.1021/om501223a

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资金

  1. EPSRC [EP/E-32575/1]
  2. EPSRC [EP/J003921/1] Funding Source: UKRI
  3. Engineering and Physical Sciences Research Council [EP/J003921/1] Funding Source: researchfish

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The synthesis, structure, and spectroscopic details of a series of beta-diketiminato lead(II) alkyl complexes are described. The Hammett correlation between the Pb-207 NMR. chemical shifts sigma(para). Hammett constant was examined computationally and found to be due to the paramagnetic shielding contribution, whereas the diamagnetic and spin-orbit coupling contributions remained fairly constant across this series of compounds.

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