期刊
ORGANOMETALLICS
卷 34, 期 5, 页码 913-917出版社
AMER CHEMICAL SOC
DOI: 10.1021/om501292k
关键词
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资金
- University of Warwick
- Australian Research Council [DP110105530, DP130100483]
- Royal Society
Reversible interaction with carbon monoxide results in the onset of dynamic atropisomerism at 298 K in an otherwise static NHC-based rhodium pincer complex, [Rh(C boolean AND N boolean AND C-(CH2)(12))(CO)][BArF4] (1, ArF = 3,5-C6H3(CF3)(2)). The mechanism of this process has been comprehensively interrogated by a combination of variable-temperature NMR spectroscopy, IR spectroscopy, and computational modeling. In addition, a structural analogue of a high-energy symmetrical intermediate species-invoked in the process but not directly observed spectroscopically-has been prepared and characterized in solution and the solid-state.
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