期刊
ORGANOMETALLICS
卷 34, 期 11, 页码 2106-2109出版社
AMER CHEMICAL SOC
DOI: 10.1021/om501204u
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan [2200009, 22350017, 2401, 25102519, 2408, 24109013]
- MEXT Project of Integrated Research on Chemical Synthesis from the Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan
- RIKEN Advanced Science Institute
- Grants-in-Aid for Scientific Research [24109013, 22000009, 26620028, 15H03777, 25288021, 15H00738, 25102519, 15K13640] Funding Source: KAKEN
A 1,2-digermabenzene bearing bulky substituents on its two germanium atoms was successfully synthesized and isolated as a stable, crystalline compound via the reaction of a digermyne precursor with 2 equiv of acetylene. Even though its molecular structure, which was revealed by X-ray crystallographic analysis, showed a trans-bent geometry for the Ge-Ge moiety, theoretical calculations Suggested substantial levels of aromaticity.
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