期刊
ORGANIC LETTERS
卷 17, 期 8, 页码 1906-1909出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00601
关键词
-
资金
- National Natural Science Foundation of China [21421002, 21332010, 21272036]
- National Basic Research Program of China [2012CB21600]
An efficient chemoselective 1,2-bis(trifluoromethylation) of alkenes with CF3SO2Na promoted by t-BuOOH/CuCl was developed. This protocol provided the first convenient preparation of 1,2-bis(trifluoromethylated) compounds by the vicinal difunctionalization of alkenes. The chemoselectivity of this reaction was accomplished by increasing the concentration of the CF3 radical.
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