期刊
ORGANIC LETTERS
卷 17, 期 6, 页码 1513-1516出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00392
关键词
-
资金
- National Natural Science Foundation of China [21332005, 21472085, 21402087]
- Qing Lan Project
- Natural Science Foundation of Jiangsu Province [BK20131267]
Rhodium(III) catalysis on water is effective for directed C-H amidation of arenes. The catalytic process is promoted by OH groups present on the hydrophobic water surface and is inefficient in all (most) common organic solvents investigated so far. In the presence of easily prepared tert-butyl 2,4-dinitrophenoxycarbamate, a new and stable nitrene source, the on water reaction can efficiently provide the desired N-Boc-aminated products with good functional group tolerance.
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