期刊
ORGANIC LETTERS
卷 17, 期 15, 页码 3730-3733出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01717
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资金
- CSIR, New Delhi [CSC-0108]
- UGC, New Delhi
A wide range of benzo[c]cinnolines are prepared through a sequential C-C and C-N bond formation by means of an oxidative C-H functionalization. The reaction proceeds via the C-arylation of 1-arylhydrazine-1,2-dicarboxylate with aryl iodide using Pd(OAc)(2)/AgOAc followed by an oxidative N-arylation in the presence of PhI/oxone in trifluoroacetic acid. It is entirely a new strategy to generate the benzo[c]cinnoline libraries with a diverse substitution pattern.
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