期刊
ORGANIC LETTERS
卷 18, 期 1, 页码 72-75出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b03290
关键词
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资金
- National Basic Research Program of China [2015CB931900, 2012CB215500]
- National Natural Science Foundation of China [21372246, 21402227, 21421002]
- Shanghai Science and Technology program [15XD1504400]
- Chinese Academy of Sciences
An efficient copper-catalyzed trifiuoromethylation of polysubstituted alkenes assisted by decarboxylation of beta,gamma-unsaturated carboxylic acids has been achieved. The reaction provides a general method to construct allylic and vinylic CF3-substituted compounds under mild conditions.
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