期刊
ORGANIC LETTERS
卷 17, 期 18, 页码 4616-4619出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02360
关键词
-
资金
- National Natural Science Foundations of China [81373290, 21322204]
- reservation-talent project of Yunnan Province [2011CI043]
Six new lanostane-related triterpenoids, kadcoccinones A-F (1-6), were isolated from Kadsura coccinea. Compound 3 possesses a novel 6/6/9-fused carbocyclic core containing a rare oxabicydo [4.3.1]decane system. Compounds 4 and 5 are isomers representing the first example of the 18(13 -> 12)-abeo-26-norlanostane triterpenoid. The absolute configurations of 1 and 4-6 were defined by X-ray diffraction and experimental ECD spectra, and that of 3 was elucidated by quantum chemical calculations. The plausible biogenetic pathway of 1-6 is postulated.
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