期刊
ORGANIC LETTERS
卷 17, 期 15, 页码 3868-3871出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01844
关键词
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资金
- NSERC
- MSFHR Career Investigator Award
- SFU Graduate Fellowships
The first total synthesis of amphirionin-4 has been achieved using a combination of cross-coupling strategies to access the polyene side chain and a chlorohydrin-based approach to construct the tetrahydrofuranol core. The remote C9-stereocenter was introduced through a Nozaki-Hiyama-Kishi coupling that proceeded with remote stereoinduction.
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