期刊
ORGANIC LETTERS
卷 17, 期 11, 页码 2716-2719出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01135
关键词
-
资金
- Addy Fund from the Andlinger Center for Energy and the Environment at Princeton University
- Princeton University
Generated in situ from air-stable cobalt precursors or readily synthesized using NaHBEt3, (PPh3)(3)CoH(N-2) was found to be an effective catalyst for the hydroboration of alkenes. Unlike previous base-metal catalysts for alkene isomerizationhydroboration which favor the incorporation of boron at terminal positions, (PPh3)(3)CoH(N-2) promotes boron incorporation adjacent to pi-systems even in substrates where the alkene is at a remote position, enabling a unique route to 1,1-diboron compounds from alpha,omega-dienes.
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