期刊
ORGANIC LETTERS
卷 17, 期 13, 页码 3283-3285出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01479
关键词
-
资金
- National Natural Science Foundation of China [21272152]
- Yang Fan Program of Shanghai Municipal Science and Technology Commission [15YE1404200]
2-Perfluoroalkylated indoles were efficiently synthesized via a one-pot cascade Michael-type addition/palladium-catalyzed intramolecular cross-dehydrogenative coupling (CDC) process, using molecular oxygen as the sole oxidant at 100 degrees C in DMSO. This process allows atom economical assembly of indole rings from inexpensive and readily available anilines and methyl perfluoroalk-2-ynoates and tolerates a broad range of functional groups.
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