期刊
ORGANIC LETTERS
卷 17, 期 16, 页码 3968-3971出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01812
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资金
- Novartis
A general and environmentally responsible method for the formation of amide/peptide bonds in an aqueous micellar medium is described. Use of uronium salt (1-cyano-2-ethoxy-2-oxoethylidenaminooxy) dimethylamino-morpholinocarbenium hexafluorophosphate (COMU) as a coupling reagent, 2,6-lutidine, and TPGS-750-M represents mild conditions associated with these valuable types of couplings, The aqueous reaction medium is recyclable leading to low E Factors.
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