期刊
ORGANIC LETTERS
卷 17, 期 24, 页码 6082-6085出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b03113
关键词
-
资金
- NSF-CAREER [CHE-1352490]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1352490] Funding Source: National Science Foundation
A direct catalytic synthesis of substituted alpha-benzyloxyamino-gamma-butyrolactones is reported, starting from simple oxime acids and alkenes. The substituted O-benzyloxime acid starting materials are cyclized with oxidizable alkenes, via Polar Radical Crossover Cycloaddition (PRCC) reactions. The catalytic reaction is carried out using the Fukuzumi acridinium photooxidant and substoichiometric amounts of a redox-active cocatalyst. The utility of this method has been demonstrated through the use of 3 oxime acids and 19 oxidizable olefins.
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