期刊
ORGANIC LETTERS
卷 17, 期 24, 页码 6090-6093出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b03116
关键词
-
资金
- South University of Science and Technology of China [FRG-SUSTC1501A-58]
A novel difunctionalization reaction is described. It uses N-trifluoromethylthio-4-nitrophthalimide as the reagent, which serves as both the nitrogen and SCF3 sources. In the presence of DABCO (1,4-diazabicyclo[2.2.2]octane), the nitrogen and SCF3 groups can be incorporated into alpha,beta-unsaturated carbonyl compounds easily and give versatile beta-amino ketones and esters in good yields. This difunctionalization reaction features mild reaction conditions, high atom-economy, and efficient access to alpha-SCF3 amino acids
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